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ChemInform Abstract: Hydroxy-Directed Regio- and Diastereoselective [2 + 2] Photocycloaddition (Paterno—Buechi Reaction) of Benzophenone to Chiral Allylic Alcohols.

✍ Scribed by Waldemar Adam; Karl Peters; Eva Maria Peters; Veit R. Stegmann

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200026047

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ChemInform Abstract: Regio- and Diastereoselective Ene Reaction of 4-Phenyl-1,2,4-triazoline-3,5-dione with Chiral Allylic Alcohols and Their Derivatives.

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Regio-and Diastereoselective Ene Reaction of 4-Phenyl-1,2,4triazoline-3,5-dione with Chiral Allylic Alcohols and Their Derivatives. -Allylic alcohols and their methyl ethers and acetates react with triazolinedione (II) with complete regioselectivity and, in most cases, with high diastereoselectivit