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ChemInform Abstract: Hydrated Nickel(II) Halides Mediated Ring Opening Reaction with N-Tosylaziridines.

โœ Scribed by Wan Xuan Zhang; Wei Gang Hu; Li Su; Li Qin Liu


Book ID
112046720
Publisher
John Wiley and Sons
Year
2012
Weight
28 KB
Volume
43
Category
Article
ISSN
0931-7597

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Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides. -Eu(dpm) 3 is found to be the best reagent for ring-opening reaction of epoxides with acyl halides. In the case of cyclohexene oxide (I), a trans addition produces (III) stereoselectively. Propylene oxide affords a mixture of