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ChemInform Abstract: Highly Water-Soluble Arene-Ruthenium(II) Complexes: Application to Catalytic Isomerization of Allylic Alcohols in Aqueous Medium.

✍ Scribed by Beatriz Lastra-Barreira; Josefina Diez; Pascale Crochet

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201009071

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## Abstract The water‐soluble complexes [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3n~(OCH~2~CH~2~NMe~3~)~n~}][SbF~6~]~n~ [n=1 (4a), 2 (4b) or 3 (4c)] have been prepared from the neutral precursors [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3‐n~(OCH~2~CH~2~NMe~2~)~n~}] [n=1 (2a), 2 (2b) or 3