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ChemInform Abstract: Highly Stereoselective Chelation-Controlled Allylation and Deuteration of α-Chiral α,α′-Dialkoxy Radicals.

✍ Scribed by H. NAGANO; Y. AZUMA


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Stereoselect
✍ Halszka Bielawska; Maria Michalska 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,