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ChemInform Abstract: Highly Enantioselective Synthesis of α-Amino Acid Derivatives by an NHC-Catalyzed Intermolecular Stetter Reaction.

✍ Scribed by Thierry Jousseaume; Nathalie E. Wurz; Frank Glorius

Publisher
John Wiley and Sons
Year
2011
Weight
42 KB
Volume
42
Category
Article
ISSN
0931-7597

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Highly Enantioselective Synthesis of α-A
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Dedicated to Professor Ronald Breslow on the occasion of his 80th birthday Scheme 1. Chiral NHC- [11,12] or enzyme-catalyzed [13] intermolecular asymmetric Stetter reactions. EWG = electron-withdrawing group, Ar = aromatic group, Het = heteroaromatic group, R = rest. Scheme 2. Proposed reaction path

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