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ChemInform Abstract: Highly Enantioselective Organocatalytic Synthesis of Piperidines. Formal Synthesis of (—)-Paroxetine.

✍ Scribed by Guillem Valero; Jiri Schimer; Ivana Cisarova; Jan Vesely; Albert Moyano; Ramon Rios

Publisher
John Wiley and Sons
Year
2009
Weight
26 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Enantioselec
ChemInform Abstract: Highly Enantioselective Organocatalytic Cascade Reaction for the Synthesis of Piperidines and Oxazolidines.
✍ Sylva Cihalova; Guillem Valero; Jiri Schimer; Marek Humpl; Martin Dracinsky; Alb 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 65 KB 👁 2 views

Highly Enantioselective Organocatalytic Cascade Reaction for the Synthesis of Piperidines and Oxazolidines. -Organocatalyzed Michael addition of amidomalonates, e.g. (I) and (VI), towards enals (II) followed by intramolecular hemiaminal formation provides enantioenriched piperidine derivatives (III)