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ChemInform Abstract: Highly Enantioselective Cascade Synthesis of Spiropyrazolones.

✍ Scribed by Alex Zea; Andrea-Nekane R. Alba; Andrea Mazzanti; Albert Moyano; Ramon Rios

Publisher
John Wiley and Sons
Year
2012
Weight
54 KB
Volume
43
Category
Article
ISSN
0931-7597

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Highly Enantioselective Organocatalytic Cascade Reaction for the Synthesis of Piperidines and Oxazolidines. -Organocatalyzed Michael addition of amidomalonates, e.g. (I) and (VI), towards enals (II) followed by intramolecular hemiaminal formation provides enantioenriched piperidine derivatives (III)