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ChemInform Abstract: Highly Enantioselective and Regioselective Carbonyl Reduction of Cyclic α,β-Unsaturated Ketones Using TarB-NO2 and Sodium Borohydride.

✍ Scribed by Jinsoo Kim; John Bruning; Kevin E. Park; David J. Lee; Bakthan Singaram

Publisher: John Wiley and Sons
Year: 2010
Weight: 45 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201008021

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A New Halogen-Exchange Reaction Between Sn-F and Li-X: Selective 1,2-and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides. -In dependence of the additive a highly regioselective reduction is obtained under optimized condition