Efficient Stereoselective Oxygenation of Alkanes by Peroxyacetic Acid or Hydrogen Peroxide and Acetic Acid Catalyzed by a Manganese( IV) 1,4,4,-The oxidation of unfunctionalized alkanes such as (I) is achieved by peroxyacetic acid (or H 2 O 2 /AcOH) in the presence of a dinuclear Mn(IV) complex as c
โฆ LIBER โฆ
ChemInform Abstract: Highly Efficient Utilization of Hydrogen Peroxide for Selective Oxygenation of Alkanes Catalyzed by Diiron-Substituted Polyoxometalate Precursor.
โ Scribed by N. MIZUNO; C. NOZAKI; I. KIYOTO; M. MISONO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Highly Efficient Utilization of Hydrogen Peroxide for Selective Oxygenation of Alkanes Catalyzed by Diiron-Substituted Polyoxometalate Precursor.
-The diiron-substituted polyoxometalate shown in the scheme is found to catalyze the oxygenation of alkanes with very high efficiency of hydrogen peroxide utilization (up to 99%). -(MIZUNO, N.;
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2010
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John Wiley and Sons
โ 35 KB
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