ChemInform Abstract: Highly Efficient Selective Monohydrolysis of Dialkyl Malonates and Their Derivatives.
β Scribed by Satomi Niwayama; Hanjoung Cho; Chunlei Lin
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 34 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Highly Efficient Arylation of Malonates with Diaryliodonium Salts. -The sodium salt of Ξ²-dicarbonyl compounds such as the diethyl malonates (I) readily reacts with symmetrical diaryliodonium salts (II) to yield the arylated derivatives (III). Unsymmetrical substrates [cf. (IV)] react with transfer o