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ChemInform Abstract: Highly Efficient Amphiphilic Cleavage of γ-Iodo Carbonyl Substrates with Aluminum Tris(2,6-diphenylphenoxide)/t-BuLi System.

✍ Scribed by Yuichiro Kondo; Kana Kon-i; Takashi Ooi; Keiji Maruoka

Book ID
101894217
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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Highly efficient amphiphilic cleavage of
Highly efficient amphiphilic cleavage of γ-iodo carbonyl substrates with aluminum tris(2,6-diphenylphenoxide)t-BuLi system
✍ Yuichiro Kondo; Kana Kon-i; Takashi Ooi; Keiji Maruoka 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 220 KB

A conceptually new amphiphilic cleavage of the ¢xl~ C-C bonds of y-iodo carbonyl substrates has been realized by the effective use of a combined Lewis acid/base system consisting of aluminum tris(2,6-diphenylphenoxide) (ATPH)/t-BuLi. This new amphiphilic bond cleavage reaction can be applied to a wi