ChemInform Abstract: Highly Diastereoselective Addition of Methyl 2-(N-Benzylamino)-1- cyclohexenecarboxylate to Chiral Acrylates.
β Scribed by K. HERVOUET; A. GUINGANT
- Book ID
- 112033234
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Highly Diastereoselective Intermolecular Ξ²-Addition of Alkyl Radicals to Chiral 2-(Arylsulfinyl)-2-cycloalkenones. -The reaction of cycloalkenones having chiral bulky arylsulfinyl groups proceeds with excellent diastereoselectivity. In the presence of the Lewis acids EtAlCl 2 and TiCl 2 (OiPr) 2 re
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