ChemInform Abstract: Highly Asymmetric Dihydroxylation of 1-Aryl-1′-pyridyl Alkenes.
✍ Scribed by Xin Wang; Mark Zak; Mathew Maddess; Paul O'Shea; Richard Tillyer; E. J. J. Grabowski; Paul J. Reider
- Publisher
- John Wiley and Sons
- Year
- 2000
- Weight
- 32 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Dihydroxylation of 1-Acyloxy-2(E)-alkenylphosphonates with AD-mix Reagents. Effects of 1-Acyloxy Functional Groups on the Asymmetric Dihydroxylation. -The reaction of a racemic mixture of the title phosphonates with an AD-mix-β reagent preferentially dihydroxylates the (R)-enantiomer to l