ChemInform Abstract: Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration.
β Scribed by Heather E. Burks; Laura T. Kliman; James P. Morken
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 59 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract In the presence of Ni(cod)~2~/PCy~3~, a wide range of 1,3βdienes including internal and sterically hindered ones efficiently undergo 1,4βdiboration.
Chiral monodentate ligands are important tools for the control of enantioselectivity in catalytic reactions. These compounds are particularly important when transition-metal catalysts lack sufficient coordination sites to bind a bidentate ligand and still retain activity. Along these lines, modular,