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ChemInform Abstract: Heterometallic 3d—4f Polyoxometalate Derived from the Weakly-Type Dimeric Structure.

✍ Scribed by Santiago Reinoso; Jose Ramon Galan-Mascaros


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ Santiago Reinoso; Jose Ramon Galan-Mascaros; Luis Lezama 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 23 KB

New Types of Heterometallic 3d-4f Rhomblike Core in Weakley-Like Polyoxometalates. -Cs3K4Na4[{Ce(OAc)}Cu3(H2O)(B-α-GeW9O34)2]•≈20H2O is synthesized from a suspension of K12[Cu4(H2O)2(GeW9O34)2], Ce(NH4)2(NO3)6, and CsCl in aqueous AcOH/NaOAc buffer solution (room temperature, 29% yield). The compoun