1-chloroalkynes and 1-bromohexyne undergo cycloaddition reactions with ethoxyvinylketeneiron(0) complexes to form chloro and bromocatechols. With most substituents, the halogen is incorporated ortho to the phenolic hydroxyl group regioselectively. With chloroethyne, chlorohexyne, and methyl chloropr
ChemInform Abstract: Halogenated Catechols from Cycloaddition Reactions of η4-(2-Ethoxyvinylketene)iron(0) Complexes with 1-Haloalkynes.
✍ Scribed by Jimmy Truong; Vioela Caze; Ravish K. Akhani; Gayatribahen K. Joshi; Lazaros Kakalis; Nikita Matsunaga; Wayne F. K. Schnatter
- Book ID
- 102050772
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 69 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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