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ChemInform Abstract: Ground State and Transition State Contributions to the Rates of Intramolecular and Enzymatic Reactions

โœ Scribed by Thomas C. Bruice; Felice C. Lightstone

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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The description of catalysis in terms of binding of a catalyst to the transition state propoposed by Kurz is applied to tautomerization of the a-heterocyclic ketones phenacylpyridine, phenacylpyrazine, phenacylphenanthroline and phenylacetylpyridine catalysed by protons and zinc ions. Binding consta