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ChemInform Abstract: Gold(I) Complexes of KITPHOS Monophosphines: Efficient Cycloisomerization Catalysts

✍ Scribed by A. Stephen K. Hashmi; Annette Loos; Anna Littmann; Ingo Braun; Julian Knight; Simon Doherty; Frank Rominger


Publisher
John Wiley and Sons
Year
2009
Weight
39 KB
Volume
40
Category
Article
ISSN
0931-7597

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Gold(I) Complexes of KITPHOS Monophosphi
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## Abstract magnified image Gold(I)‐triflimide (AuNTf~2~)complexes of H‐KITPHOS and __o__‐MeO‐KITPHOS have been prepared and shown to be efficient catalysts for a range of intramolecular cyclisations to afford phenols, acylindenes, alkylidene oxazoles, tetrahydropyrans and lactones, in the majorit

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1998 catalysis, phase-transfer catalysis catalysis, phase-transfer catalysis O 0020 35 -040 Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes. -Cationic gold(I) complexes, generated in situ by reaction of [ligand-AuMe] with Lewis or Broensted acids, are e