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ChemInform Abstract: Gold(I)-Catalyzed Enantioselective Synthesis of Pyrazolidines, Isoxazolidines, and Tetrahydrooxazines.

✍ Scribed by R. L. LaLonde; Z. J. Wang; M. Mba; A. D. Lackner; F. Dean Toste

Publisher
John Wiley and Sons
Year
2010
Weight
57 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Gold(I)-Catalyzed E
ChemInform Abstract: Gold(I)-Catalyzed Enantioselective Synthesis of Functionalized Indenes.
✍ Alberto Martinez; Patricia Garcia-Garcia; Manuel A. Fernandez-Rodriguez; Felix R 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 58 KB 👁 1 views

## Abstract Au/Ag‐Catalyzed cycloisomerization of a variety of o‐alkynylstyrene derivatives, e.g. (I) and (VII), proceeds with moderate to high enantioselectivity (up to 92% e.e.) in the presence of an axially chiral MeO‐biphep ligand to give alkenyl‐substituted indenes (II) and (VIII), resp., in h