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ChemInform Abstract: Gold-Catalyzed Synthesis of Bicyclo[3.2.0]heptenes via a Formal [3 + 2]/[2 + 2]-Annulation of Allylsilane with 4-Methoxybut-2-yn-1-ols.

✍ Scribed by Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
41
Category
Article
ISSN
0931-7597

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Gold-Catalyzed Synthesis of Bicyclo[3.2.
Gold-Catalyzed Synthesis of Bicyclo[3.2.0]heptenes via a Formal [3+2]/[2+2]-Annulation of Allylsilane with 4-Methoxybut-2-yn-1-ols
✍ Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 214 KB πŸ‘ 1 views

## Abstract This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.