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ChemInform Abstract: Glycosidase-Catalyzed Synthesis of Ergot Alkaloid α-Glycosides.

✍ Scribed by M. SCIGELOVA; P. SEDMERA; V. HAVLICEK; V. PRIKRYLOVA; V. KREN


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✍ B. A. ANDERSON; L. M. BECKE; R. N. BOOHER; M. E. FLAUGH; N. K. HARN; T. J. KRESS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Application of Palladium(0)-Catalyzed Processes to the Synthesis of Oxazole-Containing Partial Ergot Alkaloids. -A novel palladium(0)and copper(I)-cocatalyzed cyanation is developed to provide efficient and reproducible access to the key intermediate (V). The desired alkaloid (VIII) is obtained by c