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ChemInform Abstract: Generation and Reactivity of a 3H-Phosphaindene: The First 3H-Phosphole.

✍ Scribed by R. Alan Aitken; P. Nicholas Clasper; Neil J. Wilson

Book ID
101885275
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Generation and Reactivity of a 3H-Phosphaindene: The First 3H-Phosphole. -Gas phase pyrolysis of the P-chloro compound (I) over solid sodium carbonate produces an inseparable mixture of the title compound (II) and its known oxidation product (III). The P=C double bond in (II) is very highly hindered which makes it unreactive towards addition, cycloaddition, and dimerization. -(AITKEN, R. ALAN; CLASPER, P. NICHOLAS; WILSON,

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