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ChemInform Abstract: Functionalized Pyrrolidinones Derived from (S)-Pyroglutamic Acid.

✍ Scribed by M. J. BEARD; J. H. BAILEY; D. T. CHERRY; M. G. MOLONEY; S. B. SHIM; K. A. STATHAM; M. J. BAMFORD; R. B. LAMONT

Book ID: 112034011
Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199627149

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The ot, l~-unsaturated bicyclic lactams 3a,e, prepared from (S)-pyroglutamic acid. are useful substrates for cycloaddition reactions, giving excellent regio-and diastereocontrol; however, lactam 3e has very superior reactivity with several dienes and dipoles under mild reaction conditions.