ChemInform Abstract: Functionalized Organolithium Compounds by Sulfur—Lithium Exchange
✍ Scribed by Francisco Foubelo; Miguel Yus
- Book ID
- 102036377
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 15 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
1997 substitution reactions substitution reactions O 0040 41 -054 β-Functionalized Organolithium Compounds Through a Sulfur-Lithium Exchange. -Successive twofold lithiation of β-hydroxy or β-amino thioethers (I) with BuLi and Li-powder provides intermediate (II). They are trapped by electrophiles t
The successive reaction of different [~-hydroxy or I~-amino thioethers la-d with n-butyllithium and an excess of lithium powder and a catalytic amount of DTBB in TI-IF at -78°C leads to the
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