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ChemInform Abstract: β-Functionalized Organolithium Compounds Through a Sulfur-Lithium Exchange.

✍ Scribed by F. FOUBELO; A. GUTIERREZ; M. YUS

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

1997 substitution reactions substitution reactions O 0040 41 -054 β-Functionalized Organolithium Compounds Through a Sulfur-Lithium Exchange.

-Successive twofold lithiation of β-hydroxy or β-amino thioethers (I) with BuLi and Li-powder provides intermediate (II). They are trapped by electrophiles to give highly reactive functionalized alcohols or amines.

-(FOUBELO, F.;

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