ChemInform Abstract: Functionalized Bicyclic Alcohols by Enantioselective α-Deprotection—Rearrangement of meso-Epoxides.
✍ Scribed by David M. Hodgson; Iain D. Cameron; Martin Christlieb; Rebecca Green; Gary P. Lee; Lesley A. Robinson
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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An Enantioselective Synthesis of (-)-Allosamidin by Asymmetric Desymmetrization of a Highly Functionalized meso-Epoxide. -The enantioselective preparation of (XII) represents a formal total synthesis of (-)-allosamidin (XIII). A significant improvement compared to prior approaches affords this inte