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ChemInform Abstract: From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds.

✍ Scribed by Mark Turlington; Yuhao Du; Samuel G. Ostrum; Vishaka Santosh; Kathryne Wren; Tony Lin; Michal Sabat; Lin Pu

Publisher: John Wiley and Sons
Year: 2011
Weight: 52 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201152051

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✦ Synopsis

Abstract

Highly enantioselective addition of various 1,3‐diynes towards aromatic and aliphatic aldehydes is smoothly achieved in the system Et~2~Zn—(S)‐BINOL—Ti(O‐iPr)~4~.

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