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ChemInform Abstract: From 2-Phosphino-2H-phosphirene to 1-Phosphino-1H-phosphirene, 1λ5,2λ3-Diphosphete, and 1,2-Dihydro-1λ3,2λ3-diphosphete: An Experimental and Theoretical Study.

✍ Scribed by Muriel Sanchez; Regis Reau; Colin J. Marsden; Manfred Regitz; Guy Bertrand

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

From 2-Phosphino-2H-phosphirene to 1-Phosphino-1H-phosphirene, 1λ 5 ,2λ 3 -Diphosphete, and 1,2-Dihydro-1λ 3 ,2λ 3 -diphosphete: An Experimental and Theoretical Study.

-The formation of the title compounds from diazomethane derivative (I) and t-butylphosphaalkyne (II) via title intermediate (III) is investigated in detail. Ab initio calculations on different cyclic isomers of 1λ 5 ,2λ 3 -diphosphete (IV) are performed in this context.

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