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ChemInform Abstract: Friedel—Crafts Acylation of 2-Trimethylsilylnorbornene. Effect of Acyl Group on the Position of Attack.

✍ Scribed by Gopalpur Nagendrappa; Noor Shahina Begum

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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Surprising Catalytic Activity of Bismuth(III) Triflate in the Friedel-Crafts Acylation Reaction. -Bismuth(III) triflate is found to be a highly active catalyst for Friedel-Crafts acylations. The reaction of activated and deactivated arenes proceeds in high yields and gives mainly the p-substituted