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ChemInform Abstract: Free-Radical Cyclization in the Synthesis of a 1-Aza-5-silabicyclo(5.2. 0)nonan-9-one, a Silicon-Containing β-Lactam.

✍ Scribed by M. ALTAMURA; M. GIAMMARUCO; M. TADDEI; P. ULIVI

Book ID
112031641
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
27
Category
Article
ISSN
0931-7597

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Free-radical annelation in the synthesis
Free-radical annelation in the synthesis of bicyclic β-lactams. 1. Synthesis of 8-oxo-5-oxa-1-azabicyclo[4.2.0]octane and 9-oxo-6-oxa-1-azabicyclo[5.2.0]nonane derivatives
✍ Mario D. Bachi; Christian Hoornaert 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 199 KB

A new method for the synthesis of some fused bicyclic B-lactams based on the completion of the molecular backbone by a free-radical C-C bond forming reaction is described. Many of the synthetic approaches to the fused bicyclic molecular backbone of B-lactam antibiotics are based on the annelation of