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ChemInform Abstract: Free Radical Alkylation of Tri-O-benzoyl-6-exo-bromo-levoglucosan: Approaches to the Synthesis of Okadaic Acid.

✍ Scribed by David R. Kelly; Jassem G. Mahdi

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200215218

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Free radical alkylation of tri-O-benzoyl

Free radical alkylation of tri-O-benzoyl-6-exo-bromo-levoglucosan: approaches to the synthesis of okadaic acid

✍ David R Kelly; Jassem G Mahdi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 74 KB

Tri-O-benzoyl-6-exo-bromo-levoglucosan undergoes stereoselective free radical alkylation to give 6-exo-substituted-1,6anhydrosugars with six contiguous chiral centres.