ChemInform Abstract: Formation of a Propellanone in the Solvolysis of a 2-Oxo Bicyclic Bridgehead Compound.
β Scribed by K. TAKEUCHI; Y. OHGA; K. TOKUNAGA; A. TSUGENO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Formation of a Propellanone in the Solvolysis of a 2-Oxo Bicyclic Bridgehead Compound.
-Besides the known compounds (IV)-(VI) a new structure (III) is identified in the methanolysis of the triflate (I). A possible explanation of the formation of (III) is given. -(TAKEUCHI, K.; OHGA, Y.;
π SIMILAR VOLUMES
## Abstract Some bridgehead nitrogen compounds possessing the CH(Me)βbridgehead Nο£ΏC(O) system have been synthesised and their configurations assigned. The chemical shifts of the proton geminal to the methyl group provides evidence for the existence of a deformed chair conformation for the methyl su
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