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ChemInform Abstract: Formation and Trapping of 1,2-Dimethyleneazulene.

✍ Scribed by K. FUJIMORI; K. YAMANE; M. YASUNAMI; K. TAKASE


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Formation and Trapping of 1,2-Dimethyleneazulene. -Thermolysis of dihydrothiophene dioxide (I) gives low yield of the dimethyl compound (II) probably via an intermediate 1,2-dimethyleneazulene. This reactive intermediate can be trapped by dienophiles such as N-phenylmaleimide (III) and diethyl azodicarboxylate (V). -(FUJIMORI, K.; YAMANE, K.; YASUNAMI, M.;


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