Synthesis of Tetrahydrofurans and Pyrans via Palladium(0)-Mediated Cyclization. -Preliminary studies concerning the use of chiral ligands in the cyclization reactions lead to formation of furans with only low enantioselectivity. -(FOURNIER-NGUEFACK, CHRISTELLE; LHOSTE,
ChemInform Abstract: Formal Synthesis of Uvaricin (III) via Palladium-Mediated Double Cyclization.
β Scribed by Steven D. Burke; Lei Jiang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Enantioconvergent Formal Synthesis of Brefeldin A via Sakai-Catalyzed Cyclization. -A formal total synthesis of the antitumor agent brefeldin A (XII) is presented by asymmetric synthesis of intermediate (XI). Key steps are the asymmetric Sakai cyclization of racemic pentenal (I) and the reductive a