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ChemInform Abstract: Formal Synthesis of (.+-.)-Callosobruchusic Acid.

โœ Scribed by Ernest Wenkert; Haripada Khatuya


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Formal Synthesis
โœ J. COSSY; M. CASES; D. GOMEZ PARDO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 42 KB ๐Ÿ‘ 1 views

A Formal Synthesis of (-)-ฮฑ-Kainic Acid. -Starting from Lpyroglutamic acid (-)-(I), the known precursor (-)-(XVI) for the synthesis of the title compound is presented. The key step in this approach is the SmI 2 -mediated ketyl radical cyclization of the enecarbamate (X). Under irradiation condition