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ChemInform Abstract: First Total Synthesis and Absolute Configuration of Marine Cembrane Diterpenoid (+)-11,12-Epoxysarcophytol A.

โœ Scribed by Jiong Lan; Zuosheng Liu; Hao Yuan; Lizeng Peng; Wei-Dong Z. Li; Ying Li; Yulin Li; Albert S. C. Chan

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis and
ChemInform Abstract: Total Synthesis and Absolute Configuration of Polycavernoside A.
โœ K. FUJIWARA; A. MURAI; M. YOTSU-YAMASHITA; T. YASUMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB ๐Ÿ‘ 1 views

Total Synthesis and Absolute Configuration of Polycavernoside A. -The first total synthesis of polycavernoside A (XII), a toxin of red alga species, is presented, involving formation of the cyclic acetal (IV), lactonization of secoic acid (V) and rearrangement of the obtained 12-membered lactone (V