ChemInform Abstract: First Total Synthesis and Absolute Configuration of the Styryl Lactone Gonioheptolide A.
β Scribed by Shuchi Gupta; Murali Rajagopalan; Mamoun M. Alhamadsheh; L. M. Viranga Tillekeratne; Richard A. Hudson
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 18 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Total Synthesis and Absolute Configuration of Polycavernoside A. -The first total synthesis of polycavernoside A (XII), a toxin of red alga species, is presented, involving formation of the cyclic acetal (IV), lactonization of secoic acid (V) and rearrangement of the obtained 12-membered lactone (V