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ChemInform Abstract: First Stereoselective Total Synthesis of Decarestrictine O (IVb) via RCM Protocol.

✍ Scribed by Palakodety Radha Krishna; T. Jagannadha Rao

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
41
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

First stereoselective total synthesis of
First stereoselective total synthesis of decarestrictine O via RCM protocol
✍ Palakodety Radha Krishna; T. Jagannadha Rao πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 290 KB

A convergent first stereoselective total synthesis of decarestrictine O via RCM protocol starting from 1,3propanediol and propylene oxide is reported.

The first stereo selective total synthes
The first stereo selective total synthesis of (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer via an RCM protocol
✍ J.S. Yadav; Saibal Das; J. Satyanarayana Reddy; N. Thrimurtulu; A.R. Prasad πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 314 KB

The first total synthesis of (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer is reported from malic acid. The adopted approach is highly convergent and stereoselective. The strategy utilizes syn selective reduction and ring-closing metathesis as key steps.