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ChemInform Abstract: First Chiral Selenium Ylides Used for Asymmetric Conversion of Aldehydes into Epoxides.

✍ Scribed by Hiroya Takada; Patrick Metzner; Christian Philouze

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200209040

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Synthesis of Chiral Epoxides from Aldehydes Using Sulfur Ylide Derived from Reduced Product of Baker's Yeast Reduction. -Baker's yeast reduction of the cyclic β-keto esters (I) provides an enantiomerically pure β-hydroxy ester (II) in the presence of sulfur compounds as additives. A sulfur ylide der