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ChemInform Abstract: Facile Synthesis of α-Iodo Carbonyl Compounds and α-Iodo Dimethyl Ketals Using Molecular Iodine and Trimethylorthoformate.

✍ Scribed by J. S. Yadav; G. Kondaji; M. Shiva Ram Reddy; P. Srihari


Publisher
John Wiley and Sons
Year
2008
Weight
45 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Facile Synthesis
✍ M. S. YUSUBOV; I. A. PEREDERINA; V. D. FILIMONOV; T.-H. PARK; K.-W. CHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB

A Facile Synthesis of α-Iodo-β-nitroalkenes from Alkynes Using I 2 /NO 3 -or KI/NO 3 -. -The title synthesis is safer and more convenient than that with the known reagent I 2 /N 2 O 4 . The reaction can be applied to an internal alkyne as well as a terminal one and gives the (E) isomers as the main