ChemInform Abstract: Facile Synthesis of α-Iodo Carbonyl Compounds and α-Iodo Dimethyl Ketals Using Molecular Iodine and Trimethylorthoformate.
✍ Scribed by J. S. Yadav; G. Kondaji; M. Shiva Ram Reddy; P. Srihari
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 45 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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A Facile Synthesis of α-Iodo-β-nitroalkenes from Alkynes Using I 2 /NO 3 -or KI/NO 3 -. -The title synthesis is safer and more convenient than that with the known reagent I 2 /N 2 O 4 . The reaction can be applied to an internal alkyne as well as a terminal one and gives the (E) isomers as the main