Addition of Azaenolates to Simple, Unactivated Olefins. -The title reaction provides ketone derivatives by an one-pot, three component (zinc hydrazone, olefin, electrophile) coupling as an olefinic analogue of the aldol reaction. -(KUBOTA, K.;
ChemInform Abstract: Facile Addition of Poorly Nucleophilic Alcohols to Unactivated Alkenes.
β Scribed by D. F. SHELLHAMER; R. P. CALLAHAN; V. L. HEASLEY; M. L. DRUELINGER; R. D. CHAPMAN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Facile Addition of Poorly Nucleophilic Alcohols to Unactivated Alkenes.
-Strongly electronegatively substituted poorly nucleophilic alocohols (II) and (V) undergo efficient addition reactions to unactivated alkenes using BF 3 -etherate as catalyst.
π SIMILAR VOLUMES
Hypervalent Iodine Induced Nucleophilic Additions to Alkenes: Synthesis of 1,2-Diperchlorates. -Bis(perchlorate)iodo benzene, generated in situ from a reagent combination Mg(ClO 4 ) 2 /Ph-J(O-Ac) 2 and stable in a pure form at 25 β’ C for weeks, is found to be effective for the conversion of unactiva
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