Stereocontrolled Total Synthesis of (Β±)-Culmorin via the Intramolecular Double Michael Addition. -The stereocontrolled total synthesis of racemic culmorin (VII) is based on the intramolecular double Michael addition of the cyclopentenone (V) having an Ξ±,Ξ²-unsaturated ester moiety. -
β¦ LIBER β¦
ChemInform Abstract: Extremely Simple and Practical Synthesis of (.+-.)-Vertinolide via the Michael Addition.
β Scribed by Kunihiko Takabe; Nobuyuki Mase; Masaru Nomoto; Masanori Daicho; Tetsuo Tauchi; Hidemi Yoda
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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## Diastereo-and Enantioselective Synthesis of Vicinal Diamines via Aza-Michael Addition to Nitroalkenes. -Key step in the diastereoand enantioselective synthesis of vicinal diamines is an auxiliary-controlled diastereoselective conjugate addition of a chiral ammonia equivalent (II) to nitroalken