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ChemInform Abstract: Experimental and Theoretical Evidence for a Concerted Catalysis by Water Clusters in the Hydrolysis of Isocyanates.

✍ Scribed by G. RASPOET; NGUYEN MINH THO NGUYEN MINH THO; M. MCGARRAGHY; A. F. HEGARTY


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: First Experimental
✍ E. L. CLENNAN; D. L. DILLON πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

First Experimental Evidence for the Formation of a Silicate Anion by Intramolecular Addition of a Persulfoxide to a Trimethylsiloxy Group. -The photooxidation of Ξ±-trimethylsiloxysulfide (I) generates a persulfoxide, which rearranges to product (II) via a silicate intermediate. -