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ChemInform Abstract: First Experimental Evidence for the Formation of a Silicate Anion by Intramolecular Addition of a Persulfoxide to a Trimethylsiloxy Group.

✍ Scribed by E. L. CLENNAN; D. L. DILLON

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199849220

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✦ Synopsis

First Experimental Evidence for the Formation of a Silicate Anion by Intramolecular Addition of a Persulfoxide to a Trimethylsiloxy Group.

-The photooxidation of α-trimethylsiloxysulfide (I) generates a persulfoxide, which rearranges to product (II) via a silicate intermediate. -

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