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ChemInform Abstract: Eu(fod)3-Catalyzed Tandem Regiospecific Rearrangement of Divinyl Alkoxyacetates and Diels—Alder Reaction.

✍ Scribed by Wei-Min Dai; Wing Leung Mak; Anxin Wu

Publisher
John Wiley and Sons
Year
2000
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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ChemInform Abstract: Eu(fod)3-Catalyzed
ChemInform Abstract: Eu(fod)3-Catalyzed Rearrangement of Allylic Esters Possessing a Chelating Site. Application to Enediyne Synthesis.
✍ Wei-Min Dai; Mavis Yuk Ha Lee 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Eu(fod) 3 -Catalyzed Rearrangement of Allylic Esters Possessing a Chelating Site. Application to Enediyne Synthesis. -1,2-Dialkynyl-3-alkyl or 3-aryl allylic esters (I) possessing a chelating site undergo Eu(fod) 3 -catalyzed rearrangement to yield cis-enediynes (II) exclusively (13 examples). The