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ChemInform Abstract: Ethylenedinitramine — An Effective Catalyst in the Trimethylsilylation of Acetylenic Alcohols.

✍ Scribed by A. S. MEDVEDEVA; I. A. YAZOVTSEV; L. P. SAFRONOVA; M. M. DEMINA

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Ethylenedinitramine -An Effective Catalyst in the Trimethylsilylation of Acetylenic Alcohols.

-The reaction of hexamethyldisilazane (II) with acetylenic alcohols (I) is effectively catalyzed by ethylenedinitramine affording the silyloxyacetylenes (III). The reactivity of the alcohols is shown to depend on the steric environment of the hydroxyl group. -(MEDVEDEVA,

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