Reaction of Some Heterocyclic Ketones with Acetonitrile in Acidic Medium. -Reaction of the thiopyranone (I) with acetonitrile in the presence of sulfuric acid gives the acetamide (III) while the thiopyranone (IV) provides the diacetamide (V). In contrast to previously described 4piperidinones, no b
ChemInform Abstract: Equilibrium Acidities of Some Carbon Acids in Acetonitrile.
β Scribed by W. GALEZOWSKI; M. STANCZYK; A. JARCZEWSKI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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The ion pair acidities of several sulfones were measured on the cesium-cyclohexylamine scale. Cyclopropyl phenyl sulfone is less acidic than isopropyl phenyl sulfone in agreement with earlier results in dimethyl sulfoxide. The acidities of a series of substituted phenyl methyl sulfones show that the