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ChemInform Abstract: Epoxide Ring-Opening and Meinwald Rearrangement Reactions of Epoxides Catalyzed by Mesoporous Aluminosilicates.

โœ Scribed by Mathew W. C. Robinson; A. Matthew Davies; Richard Buckle; Ian Mabbett; Stuart H. Taylor; Andrew E. Graham

Publisher
John Wiley and Sons
Year
2009
Weight
59 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Lanthanoid-Catalyze
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โœ Y. TANIGUCHI; S. TANAKA; T. KITAMURA; Y. FUJIWARA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides. -Eu(dpm) 3 is found to be the best reagent for ring-opening reaction of epoxides with acyl halides. In the case of cyclohexene oxide (I), a trans addition produces (III) stereoselectively. Propylene oxide affords a mixture of