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ChemInform Abstract: Epoxidation of Vinylamides by Dimethyldioxirane: First Spectral Evidence for Enamide Oxides.

โœ Scribed by W. ADAM; D. REINHARDT; H.-U. REISSIG; K. PAULINI


Book ID
112028897
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Oxidation of 8-Methoxypsoralen (8-MOP) b
โœ Adam, Waldemar ;Sauter, Markus ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 233 KB

## Abstract The reaction of 8โ€methoxypsoralen (1) with dimethyldioxirane in methanol at 25^ยฐ^C yields the methanol adduct 3, namely the 2,3โ€dihydroโ€2โ€hydroxyโ€3,9โ€dimethoxyโ€7__H__โ€furo[3,2โ€__g__][1]benzopyranโ€7โ€one, whose structure was unequivocally assigned by means of spectroscopic data. Methanol