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ChemInform Abstract: Enzymes in Organic Chemistry. Part 9. Chemo-enzymatic Synthesis of Phosphonic Acid Analogues of L-Valine, L-Leucine, L-Isoleucine, L-Methionine and L-α-Aminobutyric Acid of High Enantiomeric Excess.

✍ Scribed by Friedrich Hammerschmidt; Frank Wuggenig


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enzymes in Organic
✍ M. DRESCHER; F. HAMMERSCHMIDT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Enzymes in Organic Chemistry. Part 5. First and Chemo-Enzymatic Synthesis of α-Aminooxyphosphonic Acids of High Enantiomeric Excess. -Acyloxyphosphonates (I) are resolved by lipase-catalyzed enantioselective hydrolysis with good to excellent enantiomeric excesses, if hydrolysis is stopped at 30-45%